Matches in SemOpenAlex for { <https://semopenalex.org/work/W1572828931> ?p ?o ?g. }
Showing items 1 to 49 of
49
with 100 items per page.
- W1572828931 endingPage "376" @default.
- W1572828931 startingPage "376" @default.
- W1572828931 abstract "研究了新化合物双环[3．3．1]壬烷-2,6,9-三酮以1，3-环己二酮为起始原料的三条合成路线，并对其反应机理进行了初步推测．第-条路线以1,3-环己二酮与丙烯醛发生Michael加成、分子内aldol缩合以及氧化三步得到双环[3．3．1]壬烷-2,6,9-三酮，总产率为43％．第二条路线为1,3-环己二酮先与吗啉反应生成烯胺，再与丙烯酸乙酯进行环合，以“一锅煮”法得到目标产物，产率为20％．第三条路线为1,3-环己二酮先与丙烯酸乙酯经过Michael加成，再进行酸催化分子内C-酰化得到目标产物，总产率为83％，该路线具有操作简单、条件温和、产率高及环境友好等优点．" @default.
- W1572828931 created "2016-06-24" @default.
- W1572828931 creator A5048930017 @default.
- W1572828931 creator A5066487650 @default.
- W1572828931 creator A5087763396 @default.
- W1572828931 date "2014-01-01" @default.
- W1572828931 modified "2023-10-02" @default.
- W1572828931 title "Synthesis of Bicyclo[3.3.1]nonane-2,6,9-trione" @default.
- W1572828931 doi "https://doi.org/10.6023/cjoc201309009" @default.
- W1572828931 hasPublicationYear "2014" @default.
- W1572828931 type Work @default.
- W1572828931 sameAs 1572828931 @default.
- W1572828931 citedByCount "0" @default.
- W1572828931 crossrefType "journal-article" @default.
- W1572828931 hasAuthorship W1572828931A5048930017 @default.
- W1572828931 hasAuthorship W1572828931A5066487650 @default.
- W1572828931 hasAuthorship W1572828931A5087763396 @default.
- W1572828931 hasBestOaLocation W15728289311 @default.
- W1572828931 hasConcept C155647269 @default.
- W1572828931 hasConcept C185592680 @default.
- W1572828931 hasConcept C24961977 @default.
- W1572828931 hasConcept C2778265757 @default.
- W1572828931 hasConcept C71240020 @default.
- W1572828931 hasConceptScore W1572828931C155647269 @default.
- W1572828931 hasConceptScore W1572828931C185592680 @default.
- W1572828931 hasConceptScore W1572828931C24961977 @default.
- W1572828931 hasConceptScore W1572828931C2778265757 @default.
- W1572828931 hasConceptScore W1572828931C71240020 @default.
- W1572828931 hasIssue "2" @default.
- W1572828931 hasLocation W15728289311 @default.
- W1572828931 hasOpenAccess W1572828931 @default.
- W1572828931 hasPrimaryLocation W15728289311 @default.
- W1572828931 hasRelatedWork W147062963 @default.
- W1572828931 hasRelatedWork W1966083136 @default.
- W1572828931 hasRelatedWork W1979133672 @default.
- W1572828931 hasRelatedWork W1999149222 @default.
- W1572828931 hasRelatedWork W2009929465 @default.
- W1572828931 hasRelatedWork W2027322958 @default.
- W1572828931 hasRelatedWork W2113825343 @default.
- W1572828931 hasRelatedWork W2232390547 @default.
- W1572828931 hasRelatedWork W2952613722 @default.
- W1572828931 hasRelatedWork W4200324342 @default.
- W1572828931 hasVolume "34" @default.
- W1572828931 isParatext "false" @default.
- W1572828931 isRetracted "false" @default.
- W1572828931 magId "1572828931" @default.
- W1572828931 workType "article" @default.