FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1572854145> ?p ?o ?g. }

• W1572854145 abstract "Electrospray ionization time of flight mass spectrometry (ESI-ToF-MS) is a powerful characterization technique for large nonvolatile compounds but has found limited applicability in the synthetic polymer field. Two factors currently limit the utility of ESI-ToF-MS for synthetic polymer characterization: 1) Electrospray ionization often results in multiply charged species for each component in the sample. Synthetic polymers contain a distribution of many compounds with close uniformly spaced masses. The presence of multiple m/z peaks for each mass typically results in data that is complicated and becomes increasingly complicated as the average molar mass of the sample increases. 2) Electrospray ionization is best suited for polar easily ionized species dissolved in polar solvents. The vast majority of synthetic polymers are relatively non-polar do not ionize easily and are not soluble in the polar solvents most often used for ESI. By adding easily ionizable surface active quaternary ammonium salts that associate with polymer molecules during ionization we have made significant strides in overcoming both of these limitations. By using cetyltrimethylammonium bromide (CTAB) as an additive we have been able to produce ESI-MS spectra with only singly charged charge states for the entire m/z range observable by our instrument (m/z = 0 - 20000). Data will be presented for poly(methyl methacrylate) and polystyrene samples. Weight averaged molecular weight (Mw) number averaged molecular weight (Mn) and polydispersity (PD) calculations were all in good agreement with comparative analysis using Gel Permeation Chromatography (GPC) and Gel Permeation Chromatography - Multi-Angle Light Scattering (GPC-MALS). Further for some samples multiple distributions were identified corresponding to different end groups highlighting the utility of this approach." @default.
• W1572854145 created "2016-06-24" @default.
• W1572854145 creator A5076444425 @default.
• W1572854145 date "2011-01-01" @default.
• W1572854145 modified "2023-09-22" @default.
• W1572854145 title "ELECTROSPRAY IONIZATION TIME OF FLIGHT MASS SPECTROMETRY OF POLY(METHYL METHACRYLATE) AND POLYSTYRENE USING SURFACE ACTIVE QUATERNARY AMMONIUM SALTS" @default.
• W1572854145 cites W1480562807 @default.
• W1572854145 cites W1495482938 @default.
• W1572854145 cites W1516583522 @default.
• W1572854145 cites W1858045933 @default.
• W1572854145 cites W1966314835 @default.
• W1572854145 cites W1967544219 @default.
• W1572854145 cites W1972658742 @default.
• W1572854145 cites W1974519406 @default.
• W1572854145 cites W1974732006 @default.
• W1572854145 cites W1975821475 @default.
• W1572854145 cites W1977016781 @default.
• W1572854145 cites W1980789136 @default.
• W1572854145 cites W1984687305 @default.
• W1572854145 cites W1992276902 @default.
• W1572854145 cites W1999241195 @default.
• W1572854145 cites W1999519347 @default.
• W1572854145 cites W2004627688 @default.
• W1572854145 cites W2008614042 @default.
• W1572854145 cites W2013117645 @default.
• W1572854145 cites W2014896121 @default.
• W1572854145 cites W2016717705 @default.
• W1572854145 cites W2018808382 @default.
• W1572854145 cites W2022538070 @default.
• W1572854145 cites W2025899873 @default.
• W1572854145 cites W2038803695 @default.
• W1572854145 cites W2046106892 @default.
• W1572854145 cites W2048689188 @default.
• W1572854145 cites W2049044923 @default.
• W1572854145 cites W2057455885 @default.
• W1572854145 cites W2065706159 @default.
• W1572854145 cites W2068888645 @default.
• W1572854145 cites W2088781483 @default.
• W1572854145 cites W2091851551 @default.
• W1572854145 cites W2092648803 @default.
• W1572854145 cites W2117432547 @default.
• W1572854145 cites W2121765191 @default.
• W1572854145 cites W2130566061 @default.
• W1572854145 cites W2144339524 @default.
• W1572854145 cites W2148176710 @default.
• W1572854145 cites W2160331366 @default.
• W1572854145 cites W2338965696 @default.
• W1572854145 hasPublicationYear "2011" @default.
• W1572854145 type Work @default.
• W1572854145 sameAs 1572854145 @default.
• W1572854145 citedByCount "0" @default.
• W1572854145 crossrefType "dissertation" @default.
• W1572854145 hasAuthorship W1572854145A5076444425 @default.
• W1572854145 hasConcept C113196181 @default.
• W1572854145 hasConcept C11432220 @default.
• W1572854145 hasConcept C145148216 @default.
• W1572854145 hasConcept C158117686 @default.
• W1572854145 hasConcept C162356407 @default.
• W1572854145 hasConcept C16291436 @default.
• W1572854145 hasConcept C178790620 @default.
• W1572854145 hasConcept C185592680 @default.
• W1572854145 hasConcept C188027245 @default.
• W1572854145 hasConcept C194451485 @default.
• W1572854145 hasConcept C196503311 @default.
• W1572854145 hasConcept C198291218 @default.
• W1572854145 hasConcept C2777922577 @default.
• W1572854145 hasConcept C40684141 @default.
• W1572854145 hasConcept C43617362 @default.
• W1572854145 hasConcept C521977710 @default.
• W1572854145 hasConcept C63179538 @default.
• W1572854145 hasConceptScore W1572854145C113196181 @default.
• W1572854145 hasConceptScore W1572854145C11432220 @default.
• W1572854145 hasConceptScore W1572854145C145148216 @default.
• W1572854145 hasConceptScore W1572854145C158117686 @default.
• W1572854145 hasConceptScore W1572854145C162356407 @default.
• W1572854145 hasConceptScore W1572854145C16291436 @default.
• W1572854145 hasConceptScore W1572854145C178790620 @default.
• W1572854145 hasConceptScore W1572854145C185592680 @default.
• W1572854145 hasConceptScore W1572854145C188027245 @default.
• W1572854145 hasConceptScore W1572854145C194451485 @default.
• W1572854145 hasConceptScore W1572854145C196503311 @default.
• W1572854145 hasConceptScore W1572854145C198291218 @default.
• W1572854145 hasConceptScore W1572854145C2777922577 @default.
• W1572854145 hasConceptScore W1572854145C40684141 @default.
• W1572854145 hasConceptScore W1572854145C43617362 @default.
• W1572854145 hasConceptScore W1572854145C521977710 @default.
• W1572854145 hasConceptScore W1572854145C63179538 @default.
• W1572854145 hasLocation W15728541451 @default.
• W1572854145 hasOpenAccess W1572854145 @default.
• W1572854145 hasPrimaryLocation W15728541451 @default.
• W1572854145 hasRelatedWork W1946815543 @default.
• W1572854145 hasRelatedWork W1980789136 @default.
• W1572854145 hasRelatedWork W1985940267 @default.
• W1572854145 hasRelatedWork W2011210827 @default.
• W1572854145 hasRelatedWork W2040533262 @default.
• W1572854145 hasRelatedWork W2045979572 @default.
• W1572854145 hasRelatedWork W2089214055 @default.
• W1572854145 hasRelatedWork W2090277609 @default.
• W1572854145 hasRelatedWork W2141473374 @default.
• W1572854145 hasRelatedWork W2300478836 @default.

• next