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- W1573536842 abstract "The inductive effects and polarizability of a series of 17 alkyl substituents were evaluated in theoretical terms from ab initio calculations for acid-base processes involving the corresponding alkanols. The effects allow one to account for general acid-base processes, both in the gas phase and in solution. Also, the classical inductive effect accounts for the acidity of dissolved alkanols and hence provides a straightforward explanation for the well known acidity inversion in alkanols from the gas phase to a solution. The applicability of the derived I and P values for the alkyl groups to the protonation of amines, nitriles, ethers and thiols is shown." @default.
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- W1573536842 date "1996-09-01" @default.
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- W1573536842 title "Influence of inductive effects and polarizability on the acid-base properties of alkyl compounds. Inversion of the alcohol acidity scale" @default.
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- W1573536842 doi "https://doi.org/10.1002/(sici)1099-1395(199609)9:9<652::aid-poc831>3.0.co;2-e" @default.
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