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- W1573574667 abstract "The construction, performance, and applications of nitrate-selective electrode based on l,8-bis(salicylaldiminato)-3,6-dioxaoctane Ni(II) complex as a carrier trapped in plasticized poly(vinyl chloride) (PVC) matrix were described. The influence of membrane composition, pH, and potential interfering anions was investigated based on the response of the electrode. The electrode exhibited linear response with Nernstian slope of-58.7 ± 0.7 mV per decade within the concentration range of nitrate ions of 8.0 ×10 -6 -1.0 mol L -1 . The limit of detection was determined from the intersection of the extrapolated linear segments of the calibration plot, and equaled 8.0 ×10 -6 mol L -1 . The response time of the electrode was < 15 s over the entire concentration range. The designed electrode could be used for at least three months without a significant potential drift. It exhibited good selectivity towards nitrate compared to other anions. It was applied as the indicator electrode in potentiometric determination of nitrate ions in real samples." @default.
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- W1573574667 date "2008-01-01" @default.
- W1573574667 modified "2023-09-26" @default.
- W1573574667 title "Potentiometric membrane electrode for determination of nitrate based on 1,8-bis(salicylaldiminato)-3,6-dioxaoctane Ni(II) complex" @default.
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