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- W1574200375 abstract "Only a minor yield of sulfur dioxide positive ions is eliminated from the meso- and dl-hydrobenzoin cyclic sulfite molecules under electron bombardment. Among the principal fragmentation products for both sulfites are very similar yields of ions with m/e 154 and 126, which contain sulfur most probably attached to a phenyl ring. Positive ions apparently corresponding to those of diphenylacetaldehyde, desoxybenzoin, and stilbene are minor products of the positive-ion fragmentation process of the sulfites. These three compounds along with sulfur dioxide are the products of the pyrolysis of the sulfites at 240-250°. The principal product from the meso-sulfite is desoxybenzoin, and from the dl-sulfite it is diphenylacetaldehyde. Mechanistic details are discussed." @default.
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- W1574200375 date "1966-06-01" @default.
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- W1574200375 title "Electron-bombardment and pyrolysis of meso- and<i>dl</i>-hydrobenzoin cyclic sulfites" @default.
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- W1574200375 doi "https://doi.org/10.1002/jhet.5570030221" @default.
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