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- W1574204556 abstract "Plastic crystal behavior is observed in semiconducting CsPb and NaSn at high temperature (600 and 500 C, respectively). This behavior is associated with M{sub 4}{sup 4{minus}} or A{sub 4}M{sub 4} structural units orientationally disordering about 50 C below the melting point where translational disorder sets in. This orientational disorder is different in the two phases, exhibiting jump reorientations in CsPb and a more isotropic behavior in NaSn. In other Zintl compounds such as KPb, there is a single melting point where orientational and translational disorder sets in simultaneously; the classification of the different Zintl compounds into these two different kinds of behavior will require calorimetry or neutron diffraction below the melting point. (DLC)" @default.
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- W1574204556 date "1992-09-22" @default.
- W1574204556 modified "2023-09-27" @default.
- W1574204556 title "Orientational phase transitions in alloys. [CsPb; NaSn]" @default.
- W1574204556 hasPublicationYear "1992" @default.
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