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- W1574228204 abstract "The reactions between RuH2(PPh3)4 or RuH4(PPh3)3 and 1,2-di(isopropylimino)ethane (DAD-A), 2,3-di(phenylimino)butane (DAD-C) and 1,2-di-(p-methoxyphenylimino)ethane (DAD-D) in toluene produce symmetrical trans dihydrido complexes. However the product obtained from DAD-C is difficult to isolate, and attempts to prepare it in alkanes led to the isolation of hexa-coordinate cis-dihydrido and pentacoordinate cis-dihydrido complexes in which the diazadiene is coordinated only through one end. A scheme showing the proposed reaction sequence is presented." @default.
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- W1574228204 date "1981-01-01" @default.
- W1574228204 modified "2023-09-25" @default.
- W1574228204 title "Reactions of ruthenium triphenylphosphine complexes with diazadienes" @default.
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- W1574228204 doi "https://doi.org/10.1016/s0022-328x(00)82478-x" @default.
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