Matches in SemOpenAlex for { <https://semopenalex.org/work/W1574357175> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W1574357175 endingPage "397" @default.
- W1574357175 startingPage "381" @default.
- W1574357175 abstract "Publisher Summary The stoichiometrically analogous tris(2,2’-bipyridine) and tris(1,10-phenanthroline) complexes of both iron(III) and osmium(III) have been found to undergo thermal redox and substitution reactions, particularly, in aqueous base. A figure is presented that shows ligand structures and ligand numbering schemes. When tris(diimine)iron(III), -ruthenium(III), or -osmium(III) salts are dissolved in water, reduction to the intensely colored tris(diimine) metal(II) complexes soon becomes apparent. In acid solution, this process is slow, but in alkaline solution it appears to be significantly accelerated. It is known that the kinetics of this reduction process is a complicated plethora of parallel and consecutive reactions, and that metal(II) complexes of differently oxidized diimine ligands are formed in addition to the dominant tris(diimine)metal(II) product. Reduction of these tris(diimine)metal(III) complexes in basic solution is easily monitored by conventional spectrophotometry in the visible range. The osmium(III) complexes are very robust and the free ligand has never been observed as a reaction product. The mechanisms for the first step of the diimine ligand oxidation in basic solution include the following: (1) simple electron transfer, (2) dissociation of a ligand proton, (3) adduct formation at a ligand carbon atom, and (4) dissociation of a metal–nitrogen bond." @default.
- W1574357175 created "2016-06-24" @default.
- W1574357175 creator A5004172513 @default.
- W1574357175 creator A5083285048 @default.
- W1574357175 date "1991-01-01" @default.
- W1574357175 modified "2023-10-03" @default.
- W1574357175 title "Oxidation of Coordinated Diimine Ligands in Basic Solutions of Tris(Diimine)Iron(III), -Ruthenium(III), and -Osmium(III)" @default.
- W1574357175 cites W1982373014 @default.
- W1574357175 cites W1987210149 @default.
- W1574357175 cites W1995187228 @default.
- W1574357175 cites W2006894011 @default.
- W1574357175 cites W2007625826 @default.
- W1574357175 cites W2009157859 @default.
- W1574357175 cites W2011562047 @default.
- W1574357175 cites W2035662878 @default.
- W1574357175 cites W2046470480 @default.
- W1574357175 cites W2051868025 @default.
- W1574357175 cites W2072073201 @default.
- W1574357175 cites W2075443697 @default.
- W1574357175 cites W2313367860 @default.
- W1574357175 cites W2403968712 @default.
- W1574357175 cites W243187772 @default.
- W1574357175 cites W2950809643 @default.
- W1574357175 cites W2951794441 @default.
- W1574357175 cites W3138468345 @default.
- W1574357175 doi "https://doi.org/10.1016/s0898-8838(08)60009-4" @default.
- W1574357175 hasPublicationYear "1991" @default.
- W1574357175 type Work @default.
- W1574357175 sameAs 1574357175 @default.
- W1574357175 citedByCount "7" @default.
- W1574357175 countsByYear W15743571752019 @default.
- W1574357175 crossrefType "book-chapter" @default.
- W1574357175 hasAuthorship W1574357175A5004172513 @default.
- W1574357175 hasAuthorship W1574357175A5083285048 @default.
- W1574357175 hasConcept C155647269 @default.
- W1574357175 hasConcept C161790260 @default.
- W1574357175 hasConcept C178790620 @default.
- W1574357175 hasConcept C185592680 @default.
- W1574357175 hasConcept C188027245 @default.
- W1574357175 hasConcept C2776303508 @default.
- W1574357175 hasConcept C2781014771 @default.
- W1574357175 hasConcept C540285154 @default.
- W1574357175 hasConcept C55493867 @default.
- W1574357175 hasConcept C555196967 @default.
- W1574357175 hasConcept C75473681 @default.
- W1574357175 hasConceptScore W1574357175C155647269 @default.
- W1574357175 hasConceptScore W1574357175C161790260 @default.
- W1574357175 hasConceptScore W1574357175C178790620 @default.
- W1574357175 hasConceptScore W1574357175C185592680 @default.
- W1574357175 hasConceptScore W1574357175C188027245 @default.
- W1574357175 hasConceptScore W1574357175C2776303508 @default.
- W1574357175 hasConceptScore W1574357175C2781014771 @default.
- W1574357175 hasConceptScore W1574357175C540285154 @default.
- W1574357175 hasConceptScore W1574357175C55493867 @default.
- W1574357175 hasConceptScore W1574357175C555196967 @default.
- W1574357175 hasConceptScore W1574357175C75473681 @default.
- W1574357175 hasLocation W15743571751 @default.
- W1574357175 hasOpenAccess W1574357175 @default.
- W1574357175 hasPrimaryLocation W15743571751 @default.
- W1574357175 hasRelatedWork W1574357175 @default.
- W1574357175 hasRelatedWork W1967243375 @default.
- W1574357175 hasRelatedWork W2035752597 @default.
- W1574357175 hasRelatedWork W2038225963 @default.
- W1574357175 hasRelatedWork W2062694018 @default.
- W1574357175 hasRelatedWork W2105736642 @default.
- W1574357175 hasRelatedWork W2159678375 @default.
- W1574357175 hasRelatedWork W2469670017 @default.
- W1574357175 hasRelatedWork W2952160252 @default.
- W1574357175 hasRelatedWork W3022839249 @default.
- W1574357175 isParatext "false" @default.
- W1574357175 isRetracted "false" @default.
- W1574357175 magId "1574357175" @default.
- W1574357175 workType "book-chapter" @default.