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• W1574358595 abstract "Abstract Activation involves binding of the intact CC or CX bond to the metal followed by CC or CX bond cleavage. Both aspects are considered here. The activation of CC bonds is facilitated by an enforced close approach of the CC bond to the metal or by the presence of a strong driving force such as a strained ring starting material or aromatization during the reaction. The reactivity order is: sp–sp > sp 2 –sp 2 > sp 3 –sp 3 . The activation of CX bonds occurs by a number of mechanistic pathways depending on the system. Halocarbon complexes of type RXM are often intermediates and can be isolated in favorable cases." @default.
• W1574358595 created "2016-06-24" @default.
• W1574358595 creator A5090136280 @default.
• W1574358595 date "2005-09-07" @default.
• W1574358595 modified "2023-10-17" @default.
• W1574358595 title "Carbon-Carbon & Carbon-Heteroatom Activation" @default.
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• W1574358595 doi "https://doi.org/10.1002/0470862106.ia287" @default.
• W1574358595 hasPublicationYear "2005" @default.
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