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- W1574375406 abstract "The logarithmof the rate constant for CHBr2COO− electroreduction at constant applied potential, corrected for diffuse-layer effects according to Frumkin, varies linearly with the charge density qi due to specifically adsorbed supporting ions. The rate of decrease ofwith increasing |qi| as observed in the presence of the adsorbed anions Br−, N3−, and SCN− is about 5 times less than the rate of increase ofwith increasing the charge qi due to adsorbed Tl+ cations. This behaviour, analogous to that observed in the reduction of the CCl3COO− ion [4], has been explained by considering that the time of adsorption of the electroactive anion CHBr2COO− is long enough to cause a perturbation in the distribution of the adsorbed supporting ions in the neighbourhood of the adsorbed anionic reactant." @default.
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- W1574375406 date "1978-06-01" @default.
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- W1574375406 title "Electrostatic effect of specifically adsorbed electroinactive ions upon electrode processes" @default.
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- W1574375406 doi "https://doi.org/10.1016/s0022-0728(78)80050-3" @default.
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