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- W1574403361 abstract "While diethyl malonate with diphenyliodonium chloride in t-butyl alcohol containing potassium t-butoxide gave only low yields of diethyl phenylmalonate and diethyl diphenylmalonate, reaction with 4,4′-dichlorodiphenyliodonium chloride gave good yields of the corresponding mono- and di-(4-chlorophenyl) derivatives. In methanol, ethanol and 2-propanol arylation was repressed, the main reactions now involving oxidation-reduction: dehydrogenation of the solvent and reduction of the diphenyliodonium ion. Such reactions gave ethylidene-bis-malonic ester in good yield. These observations are discussed in terms of a reaction mechanism of which the first step is electron transfer within an iodonium ion-carbanion pair (Ar2I+R−) to form a radical pair (Ar2I·R· or Ar·R·), whose fate depends in part on the solvent." @default.
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- W1574403361 date "1963-01-01" @default.
- W1574403361 modified "2023-09-25" @default.
- W1574403361 title "Diaryliodonium salts—XIX" @default.
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- W1574403361 doi "https://doi.org/10.1016/s0040-4020(01)99208-7" @default.
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