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- W1574506777 abstract "Abstract The resolution into antipodes of perhydrotriphenylene (I) (point group D 3 ) through the thermal decomposition of the optically active t-butylperoxi-carbonyl derivative is described. The olefins Δ 1 and Δ 2 -hexadecabydrotriphenylene were isolated as by-products. The optical purity of (−)I checked by the method of isotopic dilution reached 100% ORD and CD of(+) perhydrotriphenylen-2-one-the synthesis of which is described—show a positive Cotton effect. By applying the octant rule, the S -configuration has been confirmed for (+)I, as foreseen by the Brewster semiempirical rule." @default.
- W1574506777 created "2016-06-24" @default.
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- W1574506777 date "1970-01-01" @default.
- W1574506777 modified "2023-10-16" @default.
- W1574506777 title "Stereochemistry of perhydrotriphenylene—II" @default.
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- W1574506777 doi "https://doi.org/10.1016/s0040-4020(01)92760-7" @default.
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