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- W1574805594 abstract "The intramolecular acylation of 4-phenylbutyric acid was investigated as a model reaction for Friedel-Crafts acylation catalysed by zeolites in the liquid phase. This reaction is catalysed by zeolite H-Beta in 4-chlorotoluene as solvent. The catalytic ability of H-Beta was demonstrated by the fact that at reflux temperature the total turnover number (TON) was found to be 35. However, the acylation of toluene or butylbenzene with carboxylic acids was slow; the unbalanced adsorption equilibrium between the two reactants on the H-Beta (Si/Al = 12) may be a contributing factor in this case. The acylation of anisole by carboxylic acids or acid anhydrides however, was readily catalysed by zeolite H-Beta." @default.
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- W1574805594 date "1995-01-01" @default.
- W1574805594 modified "2023-10-12" @default.
- W1574805594 title "On the potential of zeolites to catalyse aromatic acylation with carboxylic acids" @default.
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- W1574805594 doi "https://doi.org/10.1016/s0167-2991(06)81921-x" @default.
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