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- W1576586039 abstract "The UV spectra of open chain mercaptals (R1R2C(SR3)2), cyclic mercaptals , n = 2,3,4), orthothioformate and a bicyclic trisulphide have been investigated. The results indicate that the spectra of these compounds can be classified into four groups which have γmax near: 235 mμ, acyclic compounds; 230≈250 mμ, 7-membered compounds; 246 mμ, 5-membered compounds; 250 mμ, 6-membered compounds, and there is a remarkable similarity of γmax within each of these four groups. These observations are interpreted in terms of the non-bonding interaction between two sulphur atoms involving their 3d orbitals, where a singlet radical structure is suggested for the photoexcited state." @default.
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- W1576586039 date "1964-01-01" @default.
- W1576586039 modified "2023-09-23" @default.
- W1576586039 title "3d-orbital resonance in divalent sulphides—VI" @default.
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- W1576586039 doi "https://doi.org/10.1016/s0040-4020(01)93230-2" @default.
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