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- W1576803227 abstract "Two groups of compounds were selected for microbial transformation studies. In the first group were carboxylic acid esters having a fixed aromatic moiety and an increasing length of the alkyl component. Ethyl esters of chlorine-substituted carboxylic acids were in the second group. Microorganisms from environmental waters and a pure culture of Pseudomonas putida U were used. The bacterial populations were monitored by plate counts, and disappearance of the parent compound was followed by gas-liquid chromatography as a function of time. The products of microbial hydrolysis were the respective carboxylic acids. Octanol-water partition coefficients ( K ow ) for the compounds were measured. These values spanned three orders of magnitude, whereas microbial transformation rate constants ( k b ) varied only 50-fold. The microbial rate constants of the carboxylic acid esters with a fixed aromatic moiety increased with an increasing length of alkyl substituents. The regression coefficient for the linear relationships between log k b and log K ow was high for group 1 compounds, indicating that these parameters correlated well. The regression coefficient for the linear relationships for group 2 compounds, however, was low, indicating that these parameters correlated poorly." @default.
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- W1576803227 date "1984-01-01" @default.
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- W1576803227 title "Microbial Transformation of Esters of Chlorinated Carboxylic Acids" @default.
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- W1576803227 doi "https://doi.org/10.1128/aem.47.1.7-11.1984" @default.
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