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• W1578114584 abstract "Three alkylated thiosemicarbazones (1–3) substituted on sulfur were synthesized using 5-bromosalicylaldehyde as starting material. The template reactions of the S-alkyl-thiosemicarbazones in the presence of dioxouranium(VI) were investigated. Six dioxouranium(VI) (1a–3b) complexes were synthesized. Propyl or allyl alcohol used as second ligand completed the seventh coordination site of . The synthesized thiosemicarbazones and template complexes were characterized by elemental analysis, UV-visible, FTIR, and 1H NMR. The structure of the dioxouranium(VI) complex, [UO2L(allylalcohol)], was studied by single-crystal diffraction. The uranium is seven-coordinate in a pentagonal-bipyramidal arrangement with two oxo groups occupying the apical positions." @default.
• W1578114584 created "2016-06-24" @default.
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• W1578114584 date "2013-10-20" @default.
• W1578114584 modified "2023-10-18" @default.
• W1578114584 title "Dioxouranium(VI) complexes with N2O2 chelating thiosemicarbazones [UO2L(R-OH)]" @default.
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• W1578114584 doi "https://doi.org/10.1080/00958972.2013.843679" @default.
• W1578114584 hasPublicationYear "2013" @default.
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