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- W1578219217 abstract "A comparative study of four series of pyrrhotite-type chalcogenide compounds Fe(7-y)M(y)X(8) (X = S, Se) with substitution of Ti or Co for iron has been performed by means of x-ray and neutron powder diffraction, and by magnetization measurements. In Fe(7-y)M(y)X(8) compounds having a ferrimagnetic order at y = 0, the substitution of either Ti or Co for iron is observed to result in a monotonous decrease of the magnetic ordering temperature, while the resultant magnetization shows a non-monotonous behavior with a minimum around y = 1.0-1.5 in all the Fe(7-y)M(y)X(8) families except Fe(7-y)Co(y)Se(8). Suppression of a magnetically ordered state with substitutions in Fe(7-y)M(y)X(8) is ascribed to nearly zero values of Ti and Co magnetic moments, while the non-monotonous changes of the resultant magnetization are explained by the compensation of the sublattice magnetizations due to the non-random substitutions in alternating metallic layers. The difference in the cation partitioning observed in Fe(7-y)Ti(y)X(8) and Fe(7-y)Co(y)X(8) is attributed to the difference in the spatial extension of Ti and Co 3d orbitals. High coercive field values (20-24 kOe) observed at low temperatures in the Ti-containing compounds Fe(7-y)Ti(y)X(8) with y ⩾ 3 are suggested to result from the enhancement of Fe orbital moment due to the Ti for Fe substitution." @default.
- W1578219217 created "2016-06-24" @default.
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- W1578219217 date "2015-06-30" @default.
- W1578219217 modified "2023-10-18" @default.
- W1578219217 title "Layer-preferential substitutions and magnetic properties of pyrrhotite-type Fe<sub>7−<i>y</i></sub><i>M</i><sub><i>y</i></sub><i>X</i><sub>8</sub>chalcogenides (<i>X</i>= S, Se;<i>M</i>= Ti, Co)" @default.
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- W1578219217 doi "https://doi.org/10.1088/0953-8984/27/28/286003" @default.
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