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- W1578442980 abstract "三建筑群,[ Pr ( NO3 ) 3 ( HL ) 2 ]( 1 ),[ Nd ( NO3 ) 3 ( HL ) 2 ]( 2 )并且[嗯( NO3 ) 3 ( HL ) 2 ] ·0 .5H2O ( 3 ),从 Schiff 配位体2-的反应被综合[( 4-methylphenylimino )甲基] -6-methoxyphenol ( C15H15NO2 , HL )与行( NO3 ) 3 ·6 H2O (行= Pr , Nd ,嗯)。由单个水晶的X光检查衍射技术的描述,元素的分析,臼齿的传导力,英尺红外,紫外力,( 1 ) H NMR 和热分析证明标题建筑群是中央行( III )离子在双性人是十坐标的中性分子顶端的反六面体棱柱几何学,由三个有二齿的 NO3 (?)阴离子向提供了在二有二齿的 Schiff ligands 的酉分的 hydroxy 和 methoxy 组的四个氧原子和六个氧原子。另外,建筑群 3 的热分解的运动机制与 TG-DTG 被决定由不可分、微分的方法的曲线。热分解反应机制的功能和运动赔偿效果的方程被获得。" @default.
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- W1578442980 date "2006-01-01" @default.
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- W1578442980 title "Syntheses, Crystal Structures and Kinetic Mechanisms of Thermal Decomposition of Rare Earth Complexes with Schiff Base Derived from o-Vanillin and p-Toluidine" @default.
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