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- W15785585 abstract "Adsorption equilibria and kinetics of benzene and p-xylene on microporous gallosilicates (Ga-MFI) were measured piezometrically to ascertain the role of Ga in the system and to compare it with Ga-free MFI structures. The intracrystalline mobility of benzene follows a diffusional mechanism throughout the entire concentration range with an energy of activation that considerably exceeds that for the Ga-free species (78 kJmol−1 and 26 kJmol−1, respectively). For p-xylene, the kinetics indicate the existence of three sorption states. Sorbing species become highly immobile at a pore filling of ca n > 4 molecules per unit cell, i.e. in the range of concentration where isotherm hysteresis occurs. The immobilization of p-xylene molecules is stronger than previously found for Ga-free species." @default.
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- W15785585 date "1993-01-01" @default.
- W15785585 modified "2023-09-30" @default.
- W15785585 title "Sorption Kinetics of Benzene and p-Xylene on Template Supported Synthesized Gallosilicates" @default.
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- W15785585 doi "https://doi.org/10.1016/s0167-2991(08)63568-5" @default.
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