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- W1578804573 abstract "CD and UV spectra of four chiral 11-cis-retinal Schiff bases obtained by condensing the aldehyde with asym. amines are used to gain structural information about the polyene conformation. The spectra are temp.-dependent indicating the same 12-s-cis/trans equil. as in 11-cis-retinal. In addn., CD absorptions arise at lower temps. whose only origin is the inherent dissym. nature of the retinylidene chromophore. CNDO/S-calcns. performed on the basis of force-field optimized geometries give results which can partially be rationalized on the basis of exptl. data. Quant. agreement is obtained in the case of chiral hydrogen-bonded dimers." @default.
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- W1578804573 date "1989-01-01" @default.
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- W1578804573 title "Structure investigation of chiral Schiff bases of 11-cis-retinal." @default.
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