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- W1579519454 abstract "We have experimentally identified a periodic‐adding transition in the shape of conversion oscillatory solutions observed during CO oxidation over Pd supported on a glass‐fiber disk‐shaped cloth catalyst in a continuous reactor. Typical thermograms exhibit a breathing motion in which a hot spot expands and contracts continuously and its temporal pattern matches the conversion oscillations.A mathematical model captures the main features of the experimentally observed patterns and characterizes the transition to complex oscillations as either period‐adding or period‐doubling. We have determined that a canard bifurcation of the fast subsystem with respect to the solid temperature (slow variable) is the source of the mixed‐mode oscillations in the full system." @default.
- W1579519454 created "2016-06-24" @default.
- W1579519454 creator A5066377004 @default.
- W1579519454 date "2004-01-01" @default.
- W1579519454 modified "2023-10-16" @default.
- W1579519454 title "Period Adding Transition in Thermal Patterns of Pd-Catalyzed CO Oxidation. Experiment and Theory" @default.
- W1579519454 doi "https://doi.org/10.1063/1.1846454" @default.
- W1579519454 hasPublicationYear "2004" @default.
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