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- W1579590908 abstract "Abstract A study has been made of the reduction of various unsaturated linkages by cell-free hydrogenase from Azotobacter vinelandii and Desulphovibrio desulphuricans in an attempt to establish a role for this enzyme in nitrogen fixation. Only the azo linkage in the azopyridines could be reduced; other azo compounds either required an artificial carrier or could not be reduced at all. This explained in terms of the electron density between the nitrogen atoms. Other linkages could not be reduced. The stimulation of reduction of 2,2′-azopyridine in the presence of metals has been studied, the effect of Cu 2+ being very marked, and a comparison has been made between a heterogeneous catalyst showing that the modes of actions are dissimilar. No reduction of molecular nitrogen was achieved." @default.
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- W1579590908 date "1961-11-01" @default.
- W1579590908 modified "2023-09-26" @default.
- W1579590908 title "Studies in the biological fixation of nitrogen" @default.
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- W1579590908 doi "https://doi.org/10.1016/0006-3002(61)90941-6" @default.
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