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- W1579955903 abstract "We present a new approach for determining the strength of the dipolar solute-induced reaction field, along with the ground- and excited-state electrostatic dipole moments and polarizability of a solvated chromophore, using exclusively one-photon and two-photon absorption measurements. We verify the approach on two benchmark chromophores N,N-dimethyl-6-propionyl-2-naphthylamine (prodan) and coumarin 153 (C153) in a series of toluene/dimethyl sulfoxide (DMSO) mixtures and find that the experimental values show good quantitative agreement with literature and our quantum-chemical calculations. Our results indicate that the reaction field varies in a surprisingly broad range, 0-10(7) V cm(-1) , and that at close proximity, on the order of the chromophore radius, the effective dielectric constant of the solute-solvent system displays a unique functional dependence on the bulk dielectric constant, offering new insight into the close-range molecular interaction." @default.
- W1579955903 created "2016-06-24" @default.
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- W1579955903 date "2015-05-08" @default.
- W1579955903 modified "2023-10-18" @default.
- W1579955903 title "Two-Photon Voltmeter for Measuring a Molecular Electric Field" @default.
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- W1579955903 doi "https://doi.org/10.1002/anie.201502157" @default.
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