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- W1580040977 abstract "Abstract C60 fullerene was converted with IBr as well as ICl. Two methods of preparation were used: Either the molten interhalogen compound was mixed up with C60, or C60 was exposed to the vapour phase of the interhalogen compounds. After removing excess IBr or ICl respectively by gentle warming, the reaction products were ascertained to have the compositions C60(IBr)2.6 and C60(ICl)3.2 X-ray diffraction and Raman spectroscopy proved these compounds to be intercalation compounds. However besides intercalation, part of the C60 balls were found to undergo halogenization or dimerization. EPR spectra show two singlet lines corresponding to the C60 + radical cation and a paramagnetic partially negatively charged interhalogen species. The C60 + signal is comparatively broad, indicating a strong coupling between paramagnetic centers." @default.
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- W1580040977 date "1998-02-01" @default.
- W1580040977 modified "2023-09-25" @default.
- W1580040977 title "Upon the Conversion of C60 Fullerene with Interhalogen Compounds" @default.
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- W1580040977 doi "https://doi.org/10.1080/10587259808045325" @default.
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