Matches in SemOpenAlex for { <https://semopenalex.org/work/W1580191362> ?p ?o ?g. }
Showing items 1 to 80 of
80
with 100 items per page.
- W1580191362 endingPage "1867" @default.
- W1580191362 startingPage "1858" @default.
- W1580191362 abstract "A reaction route accounting for the formation of levulinic acid from 5-hydroxymethylfuran-2-carbaldehyde was deduced on the basis of the mechanism previously offered by Horvat, to match the steps with more details. A newly deduced reaction route was proposed between two intermediate products within this mechanism, and the probabilities of the two mechanisms were compared by Gaussian 03 software. It was found that the conversion from the intermediate 2,3-dihydroxy-5-methyl-2,3-dihydro-furan-2-carbaldehyde (DMDFC) to 2,5-dioxo-hex-3-enal (DOHE) in the original mechanism has a lower net energy barrier than that in the newly deduced mechanism, and thus should be more preferred. The mechanism indicates that DMDFC is first protonized, followed by a proton shift process, and thereafter an OH- ion is added, completing the hydration process. Thereafter, an intramolecular H-shift reaction proceeds, leading to conversion to the intended intermediate product DOHE by the consecutive processes of isomerization and dehydration." @default.
- W1580191362 created "2016-06-24" @default.
- W1580191362 creator A5004635151 @default.
- W1580191362 creator A5004954920 @default.
- W1580191362 creator A5078046664 @default.
- W1580191362 date "2011-04-08" @default.
- W1580191362 modified "2023-10-06" @default.
- W1580191362 title "Mechanistic study of the conversion from DMDFC to DOHE in the levulinic acid formation process by theoretical approaches" @default.
- W1580191362 cites W1977822381 @default.
- W1580191362 cites W1980245408 @default.
- W1580191362 cites W2021219149 @default.
- W1580191362 cites W2035270116 @default.
- W1580191362 cites W2041142590 @default.
- W1580191362 cites W2054906387 @default.
- W1580191362 cites W2056500521 @default.
- W1580191362 cites W2486307793 @default.
- W1580191362 doi "https://doi.org/10.15376/biores.6.2.1858-1867" @default.
- W1580191362 hasPublicationYear "2011" @default.
- W1580191362 type Work @default.
- W1580191362 sameAs 1580191362 @default.
- W1580191362 citedByCount "2" @default.
- W1580191362 crossrefType "journal-article" @default.
- W1580191362 hasAuthorship W1580191362A5004635151 @default.
- W1580191362 hasAuthorship W1580191362A5004954920 @default.
- W1580191362 hasAuthorship W1580191362A5078046664 @default.
- W1580191362 hasBestOaLocation W15801913621 @default.
- W1580191362 hasConcept C121332964 @default.
- W1580191362 hasConcept C126661725 @default.
- W1580191362 hasConcept C147597530 @default.
- W1580191362 hasConcept C161790260 @default.
- W1580191362 hasConcept C178790620 @default.
- W1580191362 hasConcept C185544564 @default.
- W1580191362 hasConcept C185592680 @default.
- W1580191362 hasConcept C2778659115 @default.
- W1580191362 hasConcept C2778769901 @default.
- W1580191362 hasConcept C2780604391 @default.
- W1580191362 hasConcept C54516573 @default.
- W1580191362 hasConcept C55493867 @default.
- W1580191362 hasConcept C62520636 @default.
- W1580191362 hasConcept C65024703 @default.
- W1580191362 hasConcept C75079739 @default.
- W1580191362 hasConcept C89611455 @default.
- W1580191362 hasConceptScore W1580191362C121332964 @default.
- W1580191362 hasConceptScore W1580191362C126661725 @default.
- W1580191362 hasConceptScore W1580191362C147597530 @default.
- W1580191362 hasConceptScore W1580191362C161790260 @default.
- W1580191362 hasConceptScore W1580191362C178790620 @default.
- W1580191362 hasConceptScore W1580191362C185544564 @default.
- W1580191362 hasConceptScore W1580191362C185592680 @default.
- W1580191362 hasConceptScore W1580191362C2778659115 @default.
- W1580191362 hasConceptScore W1580191362C2778769901 @default.
- W1580191362 hasConceptScore W1580191362C2780604391 @default.
- W1580191362 hasConceptScore W1580191362C54516573 @default.
- W1580191362 hasConceptScore W1580191362C55493867 @default.
- W1580191362 hasConceptScore W1580191362C62520636 @default.
- W1580191362 hasConceptScore W1580191362C65024703 @default.
- W1580191362 hasConceptScore W1580191362C75079739 @default.
- W1580191362 hasConceptScore W1580191362C89611455 @default.
- W1580191362 hasIssue "2" @default.
- W1580191362 hasLocation W15801913621 @default.
- W1580191362 hasLocation W15801913622 @default.
- W1580191362 hasOpenAccess W1580191362 @default.
- W1580191362 hasPrimaryLocation W15801913621 @default.
- W1580191362 hasRelatedWork W1548328393 @default.
- W1580191362 hasRelatedWork W1994674083 @default.
- W1580191362 hasRelatedWork W2010461553 @default.
- W1580191362 hasRelatedWork W2064338204 @default.
- W1580191362 hasRelatedWork W2090943960 @default.
- W1580191362 hasRelatedWork W2105104340 @default.
- W1580191362 hasRelatedWork W2113541957 @default.
- W1580191362 hasRelatedWork W2256695865 @default.
- W1580191362 hasRelatedWork W2359208223 @default.
- W1580191362 hasRelatedWork W2392803822 @default.
- W1580191362 hasVolume "6" @default.
- W1580191362 isParatext "false" @default.
- W1580191362 isRetracted "false" @default.
- W1580191362 magId "1580191362" @default.
- W1580191362 workType "article" @default.