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• W1580450181 abstract "The photochemical behaviour of some cyanide complexes has been investigated at various wavelengths, with particular reference to irradiation in the ligand field spectral region. [Co(CN)6]3− in acid or in aqueous solutions undergoes a photoaquation reaction with quantum yield 0·31 independently of the wavelength of irradiation (254, 313 and 365 mμ), of the concentration of the complex (2 × 10−2−3 × 10−3 F) and of the pH of the solution (2–7·5). The complicated processes that follow the irradiation at 254, 313 and 404 mμ of [Fe(CN)6]3− both in aqueous and in acid solutions have been investigated in detail and a reaction mechanism involving a primary photoaquation reaction is proposed. [Cr(CN)6]3− undergoes a photoaquation reaction when irradiated at 313 and 365 mμ. Irradiation of [Ni(CN)4]2− (254, 313 and 365 mμ), [Pd(CN)4]2− (254 mμ) and [Pt(CN)4]2− (254 mμ) does not cause any reaction. The results obtained in this investigation and in the previous ones concerning the photochemical behaviour of [Mo(CN)8]3−, [W(CN)8]3−, [Mo(CN)8]4−, [W(CN)8]4−, [Mn(CN)6]3− and [Fe(CN)6]4− have been correlated as far as d-d irradiation is concerned; the primary step in the photoreaction appears to be always related to the nature of the electronic state obtained by irradiation even when the overall photochemical reaction is conditioned by non-spectrocopic factors." @default.
• W1580450181 created "2016-06-24" @default.
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• W1580450181 date "1966-11-01" @default.
• W1580450181 modified "2023-10-16" @default.
• W1580450181 title "Photochemistry of co-ordination compounds—XV" @default.
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• W1580450181 doi "https://doi.org/10.1016/0022-1902(66)80383-4" @default.
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