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- W1581574920 abstract "The enthalpies of combustion of crystalline 2-oxabicyclo[2.2.2]octan-3-one (1), and five different crystalline poly(oxycarbonyl-1,4-cyclohexylene) samples formed from 1 were measured at 298, 15 K by high-precision bomb calorimetry. For 1, the enthalpies of combustion and of formation were, −ΔH(c) = 3717,5 ± 1,3 kJ·mol−1 and −ΔH(c) = − 466,2 ± 1,6 kJ·mol−1. After correction for the presence of n-butyl- or tert-butoxy-end groups in the polyester samples, a consistent enthalpy of polymerisation of 1 was obtained, ΔH(c → c) = − 20,9 ± 2,3 kJ·mol−1. The enthalpy of sublimation of 1 was measured, ΔH (1) = 69,6 ± 2,1 kJ·mol−1; the value for the polyester unit was derived as 49 kJ·mol−1." @default.
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- W1581574920 date "1980-04-01" @default.
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- W1581574920 doi "https://doi.org/10.1002/macp.1980.021810413" @default.
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