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- W1581592626 abstract "Abstract The absolute configuration of (+) 3- p -tolylbutanoic acid 2 (V) previously derived by the molecular rotation method has been confirmed by the conversion of (−) 3-phenylbutanoic acid 3 4 (VIII) to the (−) dicarboxylic acid (XII) enantiomeric with the oxidation product of the acid (V). The absolute configuration of (+) 4- p -tolylpentanoic acid (XIX) is established on the basis of its synthesis from V. The absolute configuration of (−) α-curcumene (XXI and XXII), has been derived by considering the sign of rotation of the 4- p -tolylpentanoic acid obtained on degradation and confirmed by a synthesis of the enantiomeric (+) α-curcumene from (+) 3- p -tolylbutanoic acid (V). The absolute configuration of (+) γ-curcumene 5 (XXIV) has been established by considering the sign of rotation of the 4- p -tolylpentanoic acid derived from it. The absolute configuration suggested by previous workers for (+) 4- p -tolyl-1-pentanol 6 (XXVI) on the basis of calculations using the conformational asymmetry model has been confirmed." @default.
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- W1581592626 date "1965-01-01" @default.
- W1581592626 modified "2023-09-24" @default.
- W1581592626 title "Terpenoids—LXIX" @default.
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- W1581592626 doi "https://doi.org/10.1016/s0040-4020(01)93915-8" @default.
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