Matches in SemOpenAlex for { <https://semopenalex.org/work/W1581675703> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W1581675703 endingPage "103" @default.
- W1581675703 startingPage "97" @default.
- W1581675703 abstract "The synthesis of the sandwich complexes Ni(C5Me5)2 (I) from NiBr2 and LiC5Me5, and C5H5NiC5Me5 (II) which was obtained from C5Me5Ni(PPh3)Cl (VI) and TIC5H5, is described. Reactions of I and II with HBF4 do not lead to the formation of a corresponding tripledecker sandwich, but to [C5Me5Ni- (C5Me5H)]BF4 (III) and [C5H5Ni(C5Me5H)]BF4 (IV). Ni(C5Me5)2 reacts with Ni(CO)4 and with PPh3/CCl4 to yield [C5Me5NiCO]2 (V) and C5Me5Ni(PPh3)Cl (VI), respectively. Die Synthese der Sandwichkomplexe Ni(C5Me5)2 (I), ausgenhend von NiBr2 und LiC5Me5, und C5H5NiC5Me5 (II), ausgehend von C5Me5Ni(PPh3)Cl (VI) und TIC5H5, wird beschrieben. Die Reaktionen von I und II mit HBF4 führen nicht zur Bildung eines entsprechenden Tripeldeckersandwiches sondern zu [C5Me5Ni(C5Me5H)]BF4 (III) und [C5H5Ni(C5Me5H)]BF4 (IV). Ni(C5Me5)2 reagiert mit Ni(CO)4 und mit PPh3/CCl4 zu [C5Me5NiCO]2 (V) und C5Me5Ni(PPh3)Cl (VI)." @default.
- W1581675703 created "2016-06-24" @default.
- W1581675703 creator A5013297414 @default.
- W1581675703 creator A5086562220 @default.
- W1581675703 date "1980-09-01" @default.
- W1581675703 modified "2023-09-23" @default.
- W1581675703 title "Untersuchungen zur reaktivität von metall-π-komplexen" @default.
- W1581675703 cites W1965529528 @default.
- W1581675703 cites W1969502549 @default.
- W1581675703 cites W1973527902 @default.
- W1581675703 cites W1973674261 @default.
- W1581675703 cites W2000951387 @default.
- W1581675703 cites W2041033465 @default.
- W1581675703 cites W2041897994 @default.
- W1581675703 cites W2042498511 @default.
- W1581675703 cites W2043455472 @default.
- W1581675703 cites W2048867077 @default.
- W1581675703 cites W2051951334 @default.
- W1581675703 cites W2052173463 @default.
- W1581675703 cites W2055614596 @default.
- W1581675703 cites W2064250314 @default.
- W1581675703 cites W2081148662 @default.
- W1581675703 cites W2099037802 @default.
- W1581675703 cites W2133153127 @default.
- W1581675703 cites W2152628531 @default.
- W1581675703 cites W2314776735 @default.
- W1581675703 cites W4250698131 @default.
- W1581675703 cites W4385207770 @default.
- W1581675703 doi "https://doi.org/10.1016/s0022-328x(00)84668-9" @default.
- W1581675703 hasPublicationYear "1980" @default.
- W1581675703 type Work @default.
- W1581675703 sameAs 1581675703 @default.
- W1581675703 citedByCount "28" @default.
- W1581675703 countsByYear W15816757032016 @default.
- W1581675703 countsByYear W15816757032019 @default.
- W1581675703 countsByYear W15816757032022 @default.
- W1581675703 countsByYear W15816757032023 @default.
- W1581675703 crossrefType "journal-article" @default.
- W1581675703 hasAuthorship W1581675703A5013297414 @default.
- W1581675703 hasAuthorship W1581675703A5086562220 @default.
- W1581675703 hasConcept C134121241 @default.
- W1581675703 hasConcept C155647269 @default.
- W1581675703 hasConcept C178790620 @default.
- W1581675703 hasConcept C185592680 @default.
- W1581675703 hasConcept C191897082 @default.
- W1581675703 hasConcept C192562407 @default.
- W1581675703 hasConcept C504270822 @default.
- W1581675703 hasConceptScore W1581675703C134121241 @default.
- W1581675703 hasConceptScore W1581675703C155647269 @default.
- W1581675703 hasConceptScore W1581675703C178790620 @default.
- W1581675703 hasConceptScore W1581675703C185592680 @default.
- W1581675703 hasConceptScore W1581675703C191897082 @default.
- W1581675703 hasConceptScore W1581675703C192562407 @default.
- W1581675703 hasConceptScore W1581675703C504270822 @default.
- W1581675703 hasIssue "1" @default.
- W1581675703 hasLocation W15816757031 @default.
- W1581675703 hasOpenAccess W1581675703 @default.
- W1581675703 hasPrimaryLocation W15816757031 @default.
- W1581675703 hasRelatedWork W1986991025 @default.
- W1581675703 hasRelatedWork W2053866498 @default.
- W1581675703 hasRelatedWork W2097014657 @default.
- W1581675703 hasRelatedWork W2401463829 @default.
- W1581675703 hasRelatedWork W2403975342 @default.
- W1581675703 hasRelatedWork W2949184651 @default.
- W1581675703 hasRelatedWork W2950230984 @default.
- W1581675703 hasRelatedWork W2950314565 @default.
- W1581675703 hasRelatedWork W2950847194 @default.
- W1581675703 hasRelatedWork W2952649848 @default.
- W1581675703 hasVolume "198" @default.
- W1581675703 isParatext "false" @default.
- W1581675703 isRetracted "false" @default.
- W1581675703 magId "1581675703" @default.
- W1581675703 workType "article" @default.