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- W1582392114 abstract "Abstract The synthesis and structure of [MnLCl]0.5H 2 O ( 1· 0.5H 2 O, HL = 1‐benzyl‐4‐acetato‐1,4,7‐triazacyclononane) is reported. Complex 1 exists as a coordination polymer in the solid state, and the Mn II center is bonded to three amine nitrogen atoms, one carboxylate oxygen atom, a chlorido ligand, and an adjacent carboxylate group in a chelating fashion to afford a seven‐coordinate center. The dissolution of 1 in acetonitrile containing excess oxalate (ox) ions results in a monomeric species. When mixtures of 1 and oxalate ions are exposed to oxygen under ambient conditions, a dark pink EPR‐silent species is generated. The pink species is believed to be [Mn III (ox) 2 ] – , which results from the displacement of the ligand L – by an oxalate ion. The decomposition of this species ultimately results in the formation of 1 equiv. of CO 2 per oxalate ion consumed, a HCO 3 – ion, and a Mn II species. Further reaction of the resulting Mn II species with excess oxalate in the presence of oxygen leads to additional oxalate degradation." @default.
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- W1582392114 date "2015-01-08" @default.
- W1582392114 modified "2023-10-16" @default.
- W1582392114 title "Oxalate Oxidase Model Studies – Substrate Reactivity" @default.
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- W1582392114 doi "https://doi.org/10.1002/ejic.201402835" @default.
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