Matches in SemOpenAlex for { <https://semopenalex.org/work/W1582877170> ?p ?o ?g. }
- W1582877170 endingPage "325401" @default.
- W1582877170 startingPage "325401" @default.
- W1582877170 abstract "The high-pressure behavior of KIO(3) was studied up to 30 GPa using single crystal and powder x-ray diffraction, Raman spectroscopy, second harmonic generation (SHG) experiments and density functional theory (DFT)-based calculations. Triclinic KIO(3) shows two pressure-induced structural phase transitions at 7 GPa and at 14 GPa. Single crystal x-ray diffraction at 8.7(1) GPa was employed to solve the structure of the first high-pressure phase (space group R3, a = 5.89(1) Å, α = 62.4(1)°). The bulk modulus, B, of this phase was obtained by fitting a second order Birch-Murnaghan equation of state (eos) to synchrotron x-ray powder diffraction data resulting in B(exp,second) = 67(3) GPa. The DFT model gave B(DFT,second) = 70.9 GPa, and, for a third order Birch-Murnaghan eos, B(DFT,third) = 67.9 GPa with a pressure derivative of [Formula: see text]. Both high-pressure transformations were detectable by Raman spectroscopy and the observation of second harmonic signals. The presence of strong SHG signals shows that all high-pressure phases are acentric. By using different pressure media, we showed that the transition pressures are very strongly influenced by shear stresses. Earlier work on low- and high-temperature transitions was complemented by low-temperature heat capacity measurements. We found no evidence for the presence of an orientational glass, in contrast to earlier dielectric studies, but consistent with earlier low-temperature diffraction studies." @default.
- W1582877170 created "2016-06-24" @default.
- W1582877170 creator A5005302426 @default.
- W1582877170 creator A5025418746 @default.
- W1582877170 creator A5066300269 @default.
- W1582877170 creator A5072369350 @default.
- W1582877170 creator A5073883236 @default.
- W1582877170 creator A5077712758 @default.
- W1582877170 creator A5091529507 @default.
- W1582877170 date "2012-07-12" @default.
- W1582877170 modified "2023-10-18" @default.
- W1582877170 title "Phase transitions in KIO<sub>3</sub>" @default.
- W1582877170 cites W1925217469 @default.
- W1582877170 cites W1980358034 @default.
- W1582877170 cites W1981368803 @default.
- W1582877170 cites W1983874564 @default.
- W1582877170 cites W1988063120 @default.
- W1582877170 cites W1989908383 @default.
- W1582877170 cites W1994116515 @default.
- W1582877170 cites W1997126459 @default.
- W1582877170 cites W2000105804 @default.
- W1582877170 cites W2015493309 @default.
- W1582877170 cites W2016690724 @default.
- W1582877170 cites W2018302918 @default.
- W1582877170 cites W2021991072 @default.
- W1582877170 cites W2026729005 @default.
- W1582877170 cites W2036113194 @default.
- W1582877170 cites W2038321513 @default.
- W1582877170 cites W2041893040 @default.
- W1582877170 cites W2042696217 @default.
- W1582877170 cites W2047122670 @default.
- W1582877170 cites W2057583416 @default.
- W1582877170 cites W2070483768 @default.
- W1582877170 cites W2091384157 @default.
- W1582877170 cites W2093174743 @default.
- W1582877170 cites W2094819137 @default.
- W1582877170 cites W2095004367 @default.
- W1582877170 cites W2095517562 @default.
- W1582877170 cites W2131350133 @default.
- W1582877170 cites W2142024345 @default.
- W1582877170 cites W2159752439 @default.
- W1582877170 cites W2318825170 @default.
- W1582877170 cites W4240814540 @default.
- W1582877170 cites W4251454023 @default.
- W1582877170 cites W4255664171 @default.
- W1582877170 doi "https://doi.org/10.1088/0953-8984/24/32/325401" @default.
- W1582877170 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22787136" @default.
- W1582877170 hasPublicationYear "2012" @default.
- W1582877170 type Work @default.
- W1582877170 sameAs 1582877170 @default.
- W1582877170 citedByCount "13" @default.
- W1582877170 countsByYear W15828771702013 @default.
- W1582877170 countsByYear W15828771702014 @default.
- W1582877170 countsByYear W15828771702020 @default.
- W1582877170 countsByYear W15828771702021 @default.
- W1582877170 countsByYear W15828771702022 @default.
- W1582877170 countsByYear W15828771702023 @default.
- W1582877170 crossrefType "journal-article" @default.
- W1582877170 hasAuthorship W1582877170A5005302426 @default.
- W1582877170 hasAuthorship W1582877170A5025418746 @default.
- W1582877170 hasAuthorship W1582877170A5066300269 @default.
- W1582877170 hasAuthorship W1582877170A5072369350 @default.
- W1582877170 hasAuthorship W1582877170A5073883236 @default.
- W1582877170 hasAuthorship W1582877170A5077712758 @default.
- W1582877170 hasAuthorship W1582877170A5091529507 @default.
- W1582877170 hasConcept C113196181 @default.
- W1582877170 hasConcept C115624301 @default.
- W1582877170 hasConcept C120665830 @default.
- W1582877170 hasConcept C121332964 @default.
- W1582877170 hasConcept C147597530 @default.
- W1582877170 hasConcept C149288129 @default.
- W1582877170 hasConcept C152365726 @default.
- W1582877170 hasConcept C159985019 @default.
- W1582877170 hasConcept C178790620 @default.
- W1582877170 hasConcept C185039092 @default.
- W1582877170 hasConcept C185592680 @default.
- W1582877170 hasConcept C192562407 @default.
- W1582877170 hasConcept C207114421 @default.
- W1582877170 hasConcept C26873012 @default.
- W1582877170 hasConcept C30713254 @default.
- W1582877170 hasConcept C40003534 @default.
- W1582877170 hasConcept C42228675 @default.
- W1582877170 hasConcept C43617362 @default.
- W1582877170 hasConcept C44280652 @default.
- W1582877170 hasConcept C520434653 @default.
- W1582877170 hasConcept C73922627 @default.
- W1582877170 hasConcept C8010536 @default.
- W1582877170 hasConcept C94406020 @default.
- W1582877170 hasConceptScore W1582877170C113196181 @default.
- W1582877170 hasConceptScore W1582877170C115624301 @default.
- W1582877170 hasConceptScore W1582877170C120665830 @default.
- W1582877170 hasConceptScore W1582877170C121332964 @default.
- W1582877170 hasConceptScore W1582877170C147597530 @default.
- W1582877170 hasConceptScore W1582877170C149288129 @default.
- W1582877170 hasConceptScore W1582877170C152365726 @default.
- W1582877170 hasConceptScore W1582877170C159985019 @default.
- W1582877170 hasConceptScore W1582877170C178790620 @default.
- W1582877170 hasConceptScore W1582877170C185039092 @default.