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- W1583562908 abstract "The synthesis of three adducts of ferrocene boroxine (C10H9Fe)3B3O3 with dative bondsto amines (pyridine, 4-picoline, 4-aminomethyl pyridine, and p-bromoaniline), as well asto two diamines (4,4-bipyridine and 1,4-diazabicyclo[2.2.2]octane) to form bis-complexeswhich have the potential to be simple molecular rotors was completed. In a relatedproject, complexes of either diphenylborinic acid or 9-borabicyclononane with Lewisbase/ hydroxyl group pairs (picolinic acid, nicotinic acid, isonicotinic acid, picolinic acidN-oxide, nicotinic acid N-oxide, isonicotinic acid N-oxide, benzoic acid, 3,5-dibromobenzoic acid, 2-pyridinmethanol, L-Leucine, and L-Phenylalanine) were formed.These primarily intramolecular reactions formed rings of either 5 or 6 atom members.There was also evidence that some of the more geometrically challenged systems couldform dimers. The characterization of all of these complexes was performed by 1H NMRand, when possible, LCMS and single crystal x-ray diffraction." @default.
- W1583562908 created "2016-06-24" @default.
- W1583562908 creator A5020570324 @default.
- W1583562908 date "2012-01-01" @default.
- W1583562908 modified "2023-09-23" @default.
- W1583562908 title "Synthesis and characterization of boron-nitrogen datively bonded supramolecular assemblies and rotors" @default.
- W1583562908 hasPublicationYear "2012" @default.
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