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- W1584165037 abstract "From a reexamination of the X-ray studies of the crystal structures of 27 N-acyl-amino acids, peptides and their derivatives and 30 linear peptides, it is concluded that specific formation of short intermolecular hydrogen bonds (2.5 to 2.6 å) from the carboxyl OH to the N-acyl oxygen is an important feature for N-acyl-amino acids. For N-acyl-N1-amides, the formation of hydrogen bonds 2.7 to 2.9 å long between N(acyl)-H … O(amide) is strongly preferred. The dihedral angle δ between the N-acyl and carboxyl groups or adjacent amide groups shows a preference for values near 20° or 90° for N-acylamino acids and 90° for N-acyl-N'-amides." @default.
- W1584165037 created "2016-06-24" @default.
- W1584165037 creator A5027949125 @default.
- W1584165037 creator A5080440628 @default.
- W1584165037 date "2009-01-12" @default.
- W1584165037 modified "2023-10-09" @default.
- W1584165037 title "SPECIFIC CONFIGURATIONS OF HYDROGEN BONDING" @default.
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- W1584165037 doi "https://doi.org/10.1111/j.1399-3011.1978.tb02815.x" @default.
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