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- W1584452014 abstract "Abstract Palladium nanoparticles (NPs) 2–5 nm in size and preformed by thermal reduction in nitrile‐functionalized 3‐(3‐cyanopropyl)‐1‐methyl‐1 H ‐imidazol‐3‐ium hexafluorophosphate {[CN‐bmim]PF 6 } act as an in situ catalyst for carbon–carbon bond‐forming reactions of aromatic and heterocyclic halides with aryl‐ and vinyltrimethoxysilanes. A variety of biphenyl derivatives, substituted styrenes, and aromatic heterocycles were obtained in 76 to 98 % yield. We demonstrate for the first time the use of 1‐butyl‐3‐methylimidazolium fluoride as an activator of the organosilanes with easy handling, storage, and workup in comparison to conventional fluorine sources such as tetrabutylammonium fluoride, which is indispensable for Hiyama coupling. Pd NPs immobilized in [CN‐bmim]PF 6 gave high yields of the cross‐coupled products at a low catalyst loading of only 4 mol‐%, and the catalyst could be reused and recycled up to four times with only a slight loss in catalytic activity." @default.
- W1584452014 created "2016-06-24" @default.
- W1584452014 creator A5027987798 @default.
- W1584452014 creator A5044879604 @default.
- W1584452014 date "2013-07-01" @default.
- W1584452014 modified "2023-10-11" @default.
- W1584452014 title "Phosphane-Free Hiyama Cross-Coupling of Aryl and Heteroaryl Halides Catalyzed by Palladium Nanoparticles in Ionic Liquids" @default.
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- W1584452014 doi "https://doi.org/10.1002/ejoc.201300307" @default.
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