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- W1585616092 abstract "By treating silylamines (Me3SiNRH, HMe2SiNRH) with organoaluminium compounds we succeeded in synthezing several dialkylaluminium(N-organyl-N-methylsilylamides), formulated as R2Al-NRSiMe3, R2AlNRSiMe2H and , respectively. The products were characterized by various analytical methods. Possible side-reactions occurring especially with silyl-free secondary amines are discussed. Furthermore, the behavior of silylamines in the presence of complexed organoaluminium compounds is invesigated. Durch Umsetzung von Silylaminen (Me3SiNRH, HMe2SiNRH) mit Organoaluminiumverbindungen (AlR3, HAlR2) bzw. silyl-modifizierten Organoaluminiumverbindungen gelingt die Darstellung verschiedener Dialkylaluminium(N-organyl-N-methylsilylamide) der Art R2Al-NRSiMe3, R2AlNRSiMe2H bzw. . Es werden die möglichen Nebenreaktionen im Vergleich zur Umsetzung mit silylfreien sekundären Aminen diskutiert sowie die entstehenden Produkte characterisiert. Darüber hinaus wird das Verhalten von Silylaminen genenüber komplex-gebundenen Organoaluminiumverbindingen untersucht." @default.
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- W1585616092 date "1980-07-01" @default.
- W1585616092 modified "2023-10-14" @default.
- W1585616092 title "Aluminiumalkyle mit Heteroatomen" @default.
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- W1585616092 doi "https://doi.org/10.1016/s0022-328x(00)98892-2" @default.
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