FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1585639282> ?p ?o ?g. }

• W1585639282 abstract "The principal goal of this research is to produce hydrogen from biosustainable polyols, compounds containing a hydrocarbon chain with neighboring hydroxyl groups, such as glycerol or sorbitol. Hydrogen is an energy carrier which can replace oil and reduce pollution and greenhouse gas emissions when it is generated from renewable sources. At present, hydrogen is derived from fossil fuels such as natural gas, naphtha or coal. We show that hydrogen can be produced by reforming of glycerol, sorbitol, glucose or sucrose in water at a low temperature over supported metal catalysts. A thermodynamic analysis that forms the basis of the process compares aqueous phase reforming of polyols with steam reforming of alkanes. Catalyst screening involving different noble metals and different supports indicates that alumina supported platinum catalysts are effective for hydrogen production by aqueous phase reforming of polyols. In an attempt to achieve high hydrogen yields, the effects of operating temperature, pressure, and nature of the feed are studied. Higher operation temperatures favor higher hydrogen yields while hydrogen production is strongly inhibited by high system pressure. Short chain polyols have better hydrogen selectivities than long chain polyols. An effort is made to show that valuable chemicals can be derived from polyols. Glycerol and other polyols are potential sources of value-added chemicals, such as 1,2-propanediol, a major commodity chemical now obtained from petroleum derived propylene. It can be generated by an alternative renewable route through hydrogenolysis of biodiesel-derived glycerol. The effects of hydrogenolysis conditions such as reaction temperature, hydrogen pressure, water content in the feed and catalysts are evaluated. Both high temperature and high hydrogen pressure favor 1,2-propanediol formation. This research discusses biorefinery processes and shows how biosustainable polyols can be used as a source of hydrogen and of chemicals. The development of the aqueous phase reforming of polyols to produce hydrogen and the hydrogenolysis of polyols to generate value-added chemicals build a foundation for further research." @default.
• W1585639282 created "2016-06-24" @default.
• W1585639282 creator A5090815103 @default.
• W1585639282 date "2008-06-10" @default.
• W1585639282 modified "2023-09-27" @default.
• W1585639282 title "Catalytic generation of hydrogen and chemicals from biomass derived polyols" @default.
• W1585639282 cites W1504485964 @default.
• W1585639282 cites W1523548497 @default.
• W1585639282 cites W1550965069 @default.
• W1585639282 cites W1566473197 @default.
• W1585639282 cites W1568831666 @default.
• W1585639282 cites W1604980643 @default.
• W1585639282 cites W1853701712 @default.
• W1585639282 cites W1967443769 @default.
• W1585639282 cites W1969408630 @default.
• W1585639282 cites W1970628559 @default.
• W1585639282 cites W1973805979 @default.
• W1585639282 cites W1978963893 @default.
• W1585639282 cites W198361915 @default.
• W1585639282 cites W1990094194 @default.
• W1585639282 cites W1990875903 @default.
• W1585639282 cites W1991694218 @default.
• W1585639282 cites W1992892793 @default.
• W1585639282 cites W1996763933 @default.
• W1585639282 cites W1996866073 @default.
• W1585639282 cites W1998321859 @default.
• W1585639282 cites W2001521590 @default.
• W1585639282 cites W2001841291 @default.
• W1585639282 cites W2002949081 @default.
• W1585639282 cites W2003785380 @default.
• W1585639282 cites W2009594344 @default.
• W1585639282 cites W2011611926 @default.
• W1585639282 cites W2018754220 @default.
• W1585639282 cites W2024432714 @default.
• W1585639282 cites W2025568544 @default.
• W1585639282 cites W2026504782 @default.
• W1585639282 cites W2026589009 @default.
• W1585639282 cites W2031756320 @default.
• W1585639282 cites W2034573190 @default.
• W1585639282 cites W2035830496 @default.
• W1585639282 cites W2038718765 @default.
• W1585639282 cites W2043315151 @default.
• W1585639282 cites W2043787456 @default.
• W1585639282 cites W2044403953 @default.
• W1585639282 cites W2045114100 @default.
• W1585639282 cites W2045614154 @default.
• W1585639282 cites W2048555301 @default.
• W1585639282 cites W2051406607 @default.
• W1585639282 cites W2053887277 @default.
• W1585639282 cites W2057763779 @default.
• W1585639282 cites W2057802948 @default.
• W1585639282 cites W2059073950 @default.
• W1585639282 cites W2061456711 @default.
• W1585639282 cites W2062407088 @default.
• W1585639282 cites W2063358889 @default.
• W1585639282 cites W2071723001 @default.
• W1585639282 cites W2074374289 @default.
• W1585639282 cites W2080550917 @default.
• W1585639282 cites W2081221463 @default.
• W1585639282 cites W2084851675 @default.
• W1585639282 cites W2092185353 @default.
• W1585639282 cites W2095403516 @default.
• W1585639282 cites W2100447177 @default.
• W1585639282 cites W2101002205 @default.
• W1585639282 cites W2108624258 @default.
• W1585639282 cites W2115785832 @default.
• W1585639282 cites W2119433372 @default.
• W1585639282 cites W2123937325 @default.
• W1585639282 cites W2129533293 @default.
• W1585639282 cites W2139471708 @default.
• W1585639282 cites W2143981217 @default.
• W1585639282 cites W2151874657 @default.
• W1585639282 cites W2151911097 @default.
• W1585639282 cites W2161924087 @default.
• W1585639282 cites W2188122368 @default.
• W1585639282 cites W2284118597 @default.
• W1585639282 cites W2327423433 @default.
• W1585639282 cites W2328661431 @default.
• W1585639282 cites W2330898167 @default.
• W1585639282 cites W2335692529 @default.
• W1585639282 cites W256309948 @default.
• W1585639282 cites W2568341068 @default.
• W1585639282 cites W3091971648 @default.
• W1585639282 cites W567899283 @default.
• W1585639282 cites W655015582 @default.
• W1585639282 cites W1010755314 @default.
• W1585639282 cites W1489218301 @default.
• W1585639282 cites W1513517381 @default.
• W1585639282 cites W1536777296 @default.
• W1585639282 cites W1784282912 @default.
• W1585639282 cites W1862830372 @default.
• W1585639282 cites W1948580611 @default.
• W1585639282 cites W2027726425 @default.
• W1585639282 cites W2218564584 @default.
• W1585639282 cites W2526066435 @default.
• W1585639282 hasPublicationYear "2008" @default.
• W1585639282 type Work @default.
• W1585639282 sameAs 1585639282 @default.
• W1585639282 citedByCount "1" @default.
• W1585639282 countsByYear W15856392822019 @default.

• next