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- W1586287462 abstract "Expressions are derived for the potential dependence of the Warburg parameters which determine the faradaic part of the electrode admittance in the case of electrode reactions with a coupled first order preceding, following or catalytic reaction under Nernstian conditions. The theory is based on a relatively simple diffusion-layer model of the d.c. processes occurring at the dropping mercury electrode, which appears to be a good approximation to the more complicated expanding plane model. It has been shown that, after the frequency analysis of the electrode admittance, examination of the potential dependence of the parameters obtained provides valuable diagnostic information about the reaction mechanism. Directions are given for the course of such an analysis. A short extension is made to systems under non-Nernstian conditions." @default.
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- W1586287462 date "1970-07-01" @default.
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- W1586287462 title "On the impedance of galvanic cells" @default.
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