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- W1586291238 abstract "The paper presents a polarized Raman scattering study of a few-micron-size crystallite of LiBC with natural faces. The experiment on an as grown sample revealed four lattice modes with frequencies at 1176, 830, 546, and 170 ${mathrm{cm}}^{ensuremath{-}1},$ respectively. The number of observed Raman lines and their selection rules are incompatible with the assumed ${mathrm{D}}_{6mathrm{h}}$ symmetry. The modes at 1176 and $170{mathrm{cm}}^{ensuremath{-}1}$ correspond to the expected Raman active modes. In contrast to the superconducting compound ${mathrm{MgB}}_{2},$ the B-C bond stretching mode (at $1176{mathrm{cm}}^{ensuremath{-}1})$ has rather small damping. The two ``forbidden'' modes (at 830 and $546{mathrm{cm}}^{ensuremath{-}1})$ disappeared after a subsequent thermal treatment." @default.
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- W1586291238 date "2003-01-13" @default.
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- W1586291238 title "Polarized Raman spectroscopy of LiBC: Possible evidence for lower crystal symmetry" @default.
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- W1586291238 doi "https://doi.org/10.1103/physrevb.67.020504" @default.
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