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• W158636701 abstract "Publisher Summary Spectroscopy is arguably the most fundamental of the experimental physical sciences. In this chapter, a personal perspective is presented on the fascinatingly wide impact of molecular spectroscopy—in particular microwave spectroscopy—on an amazingly wide range of key areas in the sciences. In addition to its fundamental role in revealing a wealth of detailed intrinsic information about molecular structure from bond lengths to bond angles, it has also revealed intimate details of molecular dynamics, including internal rotation parameters and the effects of quantum mechanical tunnelling. It describes the original quantum mechanical work of Heisenberg on the quantum harmonic oscillator. Centrifugal distortion parameters can be analyzed to extract vibrational force field data, and quadrupole moment splittings can yield bond electron density properties. No less important has been the more general contributions of spectroscopy, for example, to the development of new areas of mainline chemistry as well as the birth of the field of interstellar chemistry and our understanding of how stars start to form. The impetus for the experiments that uncovered the existence of the fullerenes can be traced back to microwave spectroscopy studies, which had initiated radio astronomy detection of carbonaceous molecules in space. It is also interesting to note that the inventor of the maser/laser and one of the proponents of the leading theory of superconductivity were pioneers in molecular microwave spectroscopy." @default.
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• W158636701 date "2009-01-01" @default.
• W158636701 modified "2023-09-26" @default.
• W158636701 title "Old Spectroscopists Forget a Lot but They do Remember Their Lines" @default.
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• W158636701 doi "https://doi.org/10.1016/b978-0-444-53175-9.00001-5" @default.
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