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• W1586502783 abstract "The reaction between racemic ethylphenylchlorophosphine and menthol has been found to give a mixture of diastereoisomeric O-menthyl ethylphenylphosphinites (4) in unequal ratio. The diastereoisomeric content depends mainly on the tertiary amine used for the condensation. The chirality at phosphorus in the diastereoisomeric esters (4a and 4b) has been assigned by means of chemical correlation (conversion into optically active methylethylphenylphosphine oxide) and proton NMR spectra. It has been demonstrated that nucleophilic substitution at phosphorus in 4 occurs with inversion of configuration." @default.
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• W1586502783 date "1979-01-01" @default.
• W1586502783 modified "2023-10-14" @default.
• W1586502783 title "Optically active trivalent phosphorus compounds—I" @default.
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• W1586502783 doi "https://doi.org/10.1016/0040-4020(79)80040-x" @default.
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