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- W1586970462 abstract "The preparation of 1-stannacyclopentadienes via organoboration reactions of dialkynyldimethylstannanes (CH3)2Sn(CCR′)2 (R′= t-C4H9, Si(CH3)3) with BR3 (R = CH3, C2H5) is reported. A stepwise synthesis also leads to the title compounds. Reaction of 1-stannacyclopentadienes with BCl3 yields 1-boracyclopentadienes. The structures of the new compounds are discussed by means of 1H, 11B, 13C and 119Sn NMR spectroscopy. Die Synthese von 1-Stannacyclopentadienen mittels Organoborierung von Dialkinyldimethylstannanen (CH3)2Sn(CCR′)2 (R′ = t-C4H9, Si(CH3)3) mit BR3 (R = CH3, C2H5) wird berichtet and ebenso eine stufenweise Reaktion zur Darstellung der Titelverbindungen. 1-Stannacyclopentadiene reagieren mit BCl3 zu 1-Boracyclopentadienen. Die Strukturen der neuen Verbindungen werden mittels 1H-, 11B-, 13C- and 119Sn-NMR-Spektroskopie diskutiert." @default.
- W1586970462 created "2016-06-24" @default.
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- W1586970462 date "1978-03-01" @default.
- W1586970462 modified "2023-10-12" @default.
- W1586970462 title "Organoborierung von alkinylstannanen" @default.
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- W1586970462 doi "https://doi.org/10.1016/s0022-328x(00)84057-7" @default.
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