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- W1587130944 abstract "Oxygen-free dehydroaromatization of methane to benzene over Mo-based catalysts supported on MCM-41 and MCM-22 has been investigated. We herein report a new catalyst preparation procedure that involves low temperature vapor deposition of Mo in zero-valent state, using Mo(CO) 6 as precursor. In situ -carburization of Mo, using CH 4 /H 2 gas mixture led to the formation of catalytically active Mo x C species. Mo/MCM-22 was found to be highly active as almost equilibrium methane conversions were obtained both at 600 and 700°C. This catalyst was also highly selective for benzene formation at both temperature." @default.
- W1587130944 created "2016-06-24" @default.
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- W1587130944 creator A5091809100 @default.
- W1587130944 date "2005-01-01" @default.
- W1587130944 modified "2023-09-25" @default.
- W1587130944 title "Oxygen-free dehydroaromatization of methane over Mo-based catalysts supported on MCM-41 and MCM-22" @default.
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- W1587130944 doi "https://doi.org/10.1016/s0167-2991(05)80284-8" @default.
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