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- W1587481226 abstract "Intrazeolite Co-Mo binary sulfide clusters are synthesized using metal carbonyl techniques and used for the HDS of thiophene. It is revealed by means of XPS, XRF and EXAFS that catalytically active Co-Mo sulfide species are thermally stable Co2Mo2S6 clusters possessing a thiocubane structure. With Mo, Co and Co-Mo sulfides synthesized in Pd-NaY, Pd promotes the HDS activity of Co2Mo2S6 clusters through hydrogen activation. Full development of the catalytic synergy between Co and Mo is strongly suggested to require both cus Co and Mo sites." @default.
- W1587481226 created "2016-06-24" @default.
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- W1587481226 date "2000-01-01" @default.
- W1587481226 modified "2023-09-27" @default.
- W1587481226 title "Structure and catalysis in intrazeolite Co-Mo binary sulfide model clusters for hydrodesulfurization" @default.
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- W1587481226 doi "https://doi.org/10.1016/s0167-2991(00)80892-7" @default.
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