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- W1587701497 abstract "The molecular orientation of adsorbed polyimides and model compounds with respect to highly oriented pyrolytic graphite (HOPG) surfaces was determined by reflection-absorption infrared (RAIR) spectroscopy. As the thickness of the pyromellitic diimide (PMDI) films decreased, bands near 766 and 729 cm-1, which were assigned to the CNC out-of-plane bending modes, were relatively strong in the spectra, demonstrating that PMDI was adsorbed flat-down with the imide rings parallel to the HOPG surface. As the thickness of the N,N'-diphenylpyromellitic diimide (DPPMDI) films was decreased, bands near 1785 and 1722 cm-1 which were assigned to the C=O stretching modes, were relatively strong in the RAIR spectra. Moreover, bands near 869, 841, 742, and 686 cm-1 attributed to the out-of-plane bending modes of monosubstituted benzene rings became considerably stronger. It was suggested that the DPPMDI molecules nearest to the HOPG surface were adsorbed edge-on with the carbonyl groups perpendicular to the surface and w..." @default.
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- W1587701497 date "1993-01-01" @default.
- W1587701497 modified "2023-09-26" @default.
- W1587701497 title "Molecular structure of graphite-polyimide interphases" @default.
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- W1587701497 doi "https://doi.org/10.1163/156855493x00130" @default.
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