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- W1587981025 abstract "The electrochemical studies of solid 2.0 X 10 -3 M Cu(en) 2 X 2 .nH 2 O (n=0 for X=ClO 4 - , NO 3 - , SCN - , and n=1for Br - ) in dimethylsulfoxide, acetonitrile , and dimetylformamide /0.1M tetrabuthylammonium perchlorate , have been carried out by cyclic voltammetry. The electrode process shows two electro reduction and two chemical steps(CECE) mechanism. The reduction potentials of Cu(en) 2 (ClO 4 ) 2 shift in the order DMF? DMSO ? AN contrary to one’s expectation. For Cu(en) 2 (NO 3 ) 2 and Cu(en) 2 (SCN) 2 , the reduction potentials are more negative in DMSO relative to DMF as expected. In DMF, the reduction potentials Epc 1 shift anodically in the order: Cu(en) 2 (ClO 4 ) 2 ? Cu(en) 2 (NO 3 ) 2 ? Cu(en) 2 (SCN) 2 indicating that Epc 1 is also dependent on the nature of the anion, X Keywords : Cu(en) 2 X 2 .nH 2 O, Nonaqueous Solvent, Voltammogram, CECE mechanism, Reduction potential" @default.
- W1587981025 created "2016-06-24" @default.
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- W1587981025 date "2013-01-01" @default.
- W1587981025 modified "2023-09-26" @default.
- W1587981025 title "Mechanism and Cyclic Voltammetry of Cu(en)2X2.nH2O Complexes in Some Nonaqueous Solvents" @default.
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