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• W1587985942 startingPage "397" @default.
• W1587985942 abstract "Combustion of fossil fuels provides the basis for a major part of the world's energy generation. The combustion reactions are often carried out using excess air, such that the exhaust gases contain free molecular oxygen plus carbon dioxide (CO2) and water. Despite the use of excess air or oxygen, locally reducing conditions can develop and persist in large-scale combustion units. Such conditions can lead to carbon attack, as is discussed in the chapter. There is a continuing drive to improve the efficiency of combustion processes. Not only are temperatures being raised to achieve higher efficiencies, but alternative or modified technologies are being developed to reduce emissions of the greenhouse gas, CO2. The capture and sequestration of CO2 is made more feasible by using pure oxygen rather than air as oxidant, thereby eliminating nitrogen from the combustion gas. Carbon is unique among the common oxidants in that it is stable as a solid over a wide temperature range if the gas is sufficiently reducing. For this reason, the thermodynamic reference state is chosen as pure, solid graphite, for which aC = 1. If the carbon activity is less than one, but large enough to stabilize a metal carbide, the reaction is described as carburization. Such reactions are rapid and destructive. Catalysis of carbon deposition by the metal can lead to its disruption and fragmentation in an extremely rapid corrosion process known as metal dusting. Dusting mechanisms are different for ferritic and austenitic alloys, and they are discussed separately." @default.
• W1587985942 created "2016-06-24" @default.
• W1587985942 creator A5003530056 @default.
• W1587985942 date "2008-01-01" @default.
• W1587985942 modified "2023-10-16" @default.
• W1587985942 title "Chapter 9 Corrosion by Carbon" @default.
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