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- W1588185324 abstract "High magnetic field, low-temperature Zeeman measurements of the 4A2g to 4T2g zero-phonon liners of Mn4+ in Cs2SiF6 are reported. The separation of the spin-orbit components of the 4T2g term are established and are found to be an order of magnitude smaller than that predicted by static crystal-field theory. The reduction is explained in terms of Ham quenching of the off-diagonal spin-orbit interaction arising from a strong Jahn-Teller effect. Zeeman polarisations are found to be fully consistent with this Jahn-Teller model. Difficulties are, however, encountered in giving a satisfactory account of the relative intensity of the zero-phonon transitions." @default.
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- W1588185324 date "1979-12-28" @default.
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- W1588185324 title "Jahn-Teller effect in the<sup>4</sup>T<sub>2g</sub>state of Mn<sup>4+</sup>in Cs<sub>2</sub>SiF<sub>6</sub>" @default.
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- W1588185324 doi "https://doi.org/10.1088/0022-3719/12/24/020" @default.
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