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- W1588518117 abstract "Summary Monometallic silver catalysts prepared by various techniques were found to control the intramolecular selectivity of the gas phase hydrogenation of crotonaldehyde by favoring the hydrogenation of the C=O group compared to the C=C group which gave crotyl alcohol selectivities around 55 to 63%. For sol-gel derived Ag/SiO 2 catalysts the influence of the hydrolysis conditions on the structural properties has been studied. They showed a narrower Ag particle size distribution at significantly lower crystallite sizes than catalysts prepared by impregnation or precipitation-deposition. Ag catalysts further modified by (i) alloying with a late transition metal and (ii) promoting with an early transition metal or a rare earth metal have been found to increase the selevctivity towards crotyl alcohol up to 85%." @default.
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- W1588518117 date "1997-01-01" @default.
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- W1588518117 title "Selective hydrogenation of α,β-unsaturated aldehydes to allylic alcohols over supported monometallic and bimetallic Ag catalysts" @default.
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- W1588518117 doi "https://doi.org/10.1016/s0167-2991(97)80915-9" @default.
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