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- W1588933000 abstract "Measurements of the viscosity and dynamic moduli of paraffin oil in water emulsions stabilized by a partially esterified sodium polymethacrylate (PMA-pe) and comparison with the rheological properties of the same polyelectrolytes in the dissolved state indicated that the intra molecular interactions in the free molecule occur also in the adsorbed state and are virtually identical to the intermolecular interaction between PMA-pe molecules adsorbed on different emulsion droplets. Special attention is paid to the effects of pH, temperature, and the presence of methanol. It is concluded that rheological measurements on polyelectrolyte-stabilized emulsions are a powerful tool to a better understanding of the nature of the interaction forces in the polyelectrolyte used. In the case of PMA-pe, hydrophobic bonding was found to be responsible for the occurrence of a compact conformation at low pH." @default.
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- W1588933000 date "1978-01-01" @default.
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- W1588933000 title "Rheology of polyelectrolyte-stabilized emulsions" @default.
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- W1588933000 doi "https://doi.org/10.1016/0021-9797(78)90039-5" @default.
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