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- W1588991947 abstract "The solution of the strongly acidic polyelectrolyte poly(2-acrylamido-2-methylpropanesulfonic acid) in N,N-dimethylformamide or N,N-dimethylacetamide is accompanied by a simultaneous reaction of amidation of the sulfonic acid to the corresponding sulfonamide groups. Various compositions of binary copolymers poly[(2-acrylamido-2-methylpropanesulfonic acid)-co-(2-acrylamido-2-methylpropane-N,N-dimethylsulfonamide)] up to high amidation conversions of 98–99% were synthesized and characterized. The amidation of the sulfonic acid groups appears to be a common reaction for different copolymers having 2-acrylamido-2-methylpropanesulfonic acid moieties but fails with the free monomer. Das Auflösen des stark sauren Polyelektrolyten Poly(2-acrylamido-2-methylpropansulfonsäure) in N,N-Dimethylformamid oder N,N-Dimethylacetamid geht mit einer Amidierung der Sulfonsäuregruppen zu Sulfonamidgruppen mit Umsätzen bis zu 99% einher. Dies scheint eine allgemeine Reaktion von Polymeren mit 2-Acrylamido-2-methylpropansulfonsäure-Gruppen zu sein; sie gelingt nicht mit dem freien Monomeren." @default.
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- W1588991947 date "1996-03-01" @default.
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- W1588991947 doi "https://doi.org/10.1002/apmc.1996.052360107" @default.
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